Determination of Sr in highly radioactive aqueous samples via conversion to a kinetically stable 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid complex followed by concentration-separation-fractionation based on capillary electrophoresis-liquid scintillation

Ouchi, Kazuki; Haraga, Tomoko; Hirose, Kazuki*; Kurosawa, Yuika*; Sato, Yoshiyuki; Shibukawa, Masami*; Saito, Shingo*

Analytica Chimica Acta, 1298, p.342399_1 - 342399_7, 2024/04

https://doi.org/10.1016/j.aca.2024.342399

Given that conventional methods of high-dose sample analysis pose substantial exposure risks and generate large amounts of secondary radioactive waste, faster procedures allowing for decreased radiation emission are highly desirable. To address this need, we developed a Sr quantitation technique that is based on liquid scintillation counting-coupled capillary transient isotachophoresis (ctITP) with two-point detection and relies on the rapid concentration, separation, and fractionation of 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid (DOTA)-complexed Sr in a single run. This method, which allows for the handling of high-dose radioactive specimens at the microliter level and is substantially faster than conventional ion-exchange protocols, was used to selectively quantify Sr in real high-dose waste. The successful concentration-separation in ctITP was ascribed to the inertness of the Sr-DOTA complex to dissociation.

Development of technology for rapid analysis of strontium-90 with low isotopic abundance using laser resonance ionization (Contract research); FY2020 Nuclear Energy Science & Technology and Human Resource Development Project

Collaborative Laboratories for Advanced Decommissioning Science; The University of Tokyo*

JAEA-Review 2022-014, 106 Pages, 2022/08

JAEA-Review-2022-014.pdf:10.42MB

The Collaborative Laboratories for Advanced Decommissioning Science (CLADS), Japan Atomic Energy Agency (JAEA), had been conducting the Nuclear Energy Science & Technology and Human Resource Development Project (hereafter referred to "the Project") in FY2020. The Project aims to contribute to solving problems in the nuclear energy field represented by the decommissioning of the Fukushima Daiichi Nuclear Power Station, Tokyo Electric Power Company Holdings, Inc. (TEPCO). For this purpose, intelligence was collected from all over the world, and basic research and human resource development were promoted by closely integrating/collaborating knowledge and experiences in various fields beyond the barrier of conventional organizations and research fields. The sponsor of the Project was moved from the Ministry of Education, Culture, Sports, Science and Technology to JAEA since the newly adopted proposals in FY2018. On this occasion, JAEA constructed a new research system where JAEA-academia collaboration is reinforced and medium-to-long term research/development and human resource development contributing to the decommissioning are stably and consecutively implemented. Among the adopted proposals in FY2018, this report summarizes the research results of the "Development of technology for rapid analysis of strontium-90 with low isotopic abundance using laser resonance ionization" conducted from FY2018 to FY2021 (this contract was extended to FY2021). Since the final year of this proposal was FY2021, the results for four fiscal years were summarized. The present study aims to develop a rapid analysis technique for strontium-90 using diode laser-based resonance ionization with elemental and isotopic selectivity. Strontium-90 is one of the major difficult-to-measure nuclides released into the environment due to the accident at TEPCO's Fukushima Daiichi Nuclear Power Station.

Development of technology for rapid analysis of strontium-90 with low isotopic abundance using laser resonance ionization (Contract research); FY2018 Center of World Intelligence Project for Nuclear Science/Technology and Human Resource Development

Collaborative Laboratories for Advanced Decommissioning Science; The University of Tokyo*

JAEA-Review 2019-027, 70 Pages, 2020/01

JAEA-Review-2019-027.pdf:5.18MB

JAEA/CLADS, had been conducting the Center of World Intelligence Project for Nuclear Science/Technology and Human Resource Development (hereafter referred to "the Project") in FY2018. The Project aims to contribute to solving problems in nuclear energy field represented by the decommissioning of the Fukushima Daiichi Nuclear Power Station, Tokyo Electric Power Company Holdings, Inc. For this purpose, intelligence was collected from all over the world, and basic research and human resource development were promoted by closely integrating/collaborating knowledge and experiences in various fields beyond the barrier of conventional organizations and research fields. The sponsor of the Project was moved from the Ministry of Education, Culture, Sports, Science and Technology to JAEA since the newly adopted proposals in FY2018. On this occasion, JAEA constructed a new research system where JAEA-academia collaboration is reinforced and medium-to-long term research/development and human resource development contributing to the decommissioning are stably and consecutively implemented. Among the adopted proposals in FY2018, this report summarizes the research results of the "Development of Technology for Rapid Analysis of Strontium-90 with Low Isotopic Abundance Using Laser Resonance Ionization". In this study, we will develop a rapid analysis technique for strontium-90 using diode laser-based resonance ionization with elemental and isotopic selectivity. Strontium-90 is one of the major difficult-to-measure nuclides released into the environment due to the accident at Tokyo Electric Power Company (TEPCO)'s Fukushima Daiichi Nuclear Power Station. Our method is particularly intended for real samples which contain high concentrations of strontium stable isotopes such as marine samples.

Estimation of dietary intake of strontium-90 from excreta analysis

Journal of Nuclear Science and Technology, 1(7), p.255 - 263, 1964/00

https://doi.org/10.3327/jnst.1.255

no abstracts in English